道行くんの研究成果が Chem. Commum. に掲載


道行くんの研究成果が、イギリス化学会誌の Chamical Communications への掲載が決定しました。本論文は、道行くんが第一著者として執筆した論文です。

 

Reductive amidation of alkyl tosylates with isocyanates by Ni/Co-dual catalytic system

Takuya Michiyuki, Itaru Osaka, Kimihiro Komeyama* 

Chem. Commun.2020, DOI: 10.1039/C9CC09377J

Abstract: Reductive amidation of alkyl tosylates with isocyanates using the Ni/Co-dual catalytic system is disclosed. The method proceeds efficiently under mild conditions, giving rise to the corresponding alkyl amides. Notably, the protocol can discriminate the steric environment of two alkyl tosylate moieties, enabling regioselective mono-amidation at the less-bulky site.